Online ISSN: 1884-4111 Print ISSN: 0033-8303
Radioisotopes 66(10): 437-449 (2017)

特集Special Issues

6 放射線化学による反応機構の解明6 Radiation Chemical Studies on Reaction Mechanisms

大阪大学産業科学研究所The Institute of Scientific and Industrial Research, Osaka University ◇ 567–0047 大阪府茨木市美穂ヶ丘8–1 ◇ 8–1 Mihogaoka, Ibaraki-shi, Osaka 567–0047, Japan

発行日:2017年10月15日Published: October 15, 2017


Radiation chemical methods have been applied to various studies on chemical reactions for years, because redox active species generated by radiolysis can efficiently generate reaction intermediates of target chemical reactions. In this article, basic aspects of radiation chemical methods are summarized first. Then, our experimental results on reaction mechanistic studies are summarized as examples for wide applicability of radiation chemical methods.

Key words: pulse radiolysis; γ-ray radiolysis; π-conjugated materials; charge delocalization; oxidation and reduction processes of biomaterials; reaction mechanism; reactive intermediate

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